Poly[[aquacalcium(II)]-μ4-1H-imidazole-4,5-dicarboxylato]
نویسندگان
چکیده
In the title compound, [Ca(C(5)H(2)N(2)O(4))(H(2)O)](n), the Ca(2+) cations are eigthtfold coordinated by six O atoms and one N atom of four symmetry-related anions and one water mol-ecule within an irregular polyhedron. These CaO(7)N polyhedra are connected via the anions into a three-dimensional network. The anions are additionally linked by N-H⋯O and O-H⋯O hydrogen bonding.
منابع مشابه
Poly[[tetraaquabis(μ3-1H-imidazole-4,5-dicarboxylato)tetrakis(μ2-1H-imidazole-4,5-dicarboxylato)tricobalt(II)diytterbium(III)] dihydrate]
The asymmetric unit of the title compound, {[Co(3)Yb(2)(C(5)H(2)N(2)O(4))(6)(H(2)O)(4)]·2H(2)O}(n), contains one Yb(III) ion, two Co(II) ions (one situated on an inversion centre), three imidazole-4,5-dicarboxyl-ate ligands, two coordinated water mol-ecules and one uncoordinated water mol-ecule. The Yb(III) ion is seven-coordinated, in a monocapped trigonal prismatic coordination geometry, by s...
متن کاملPoly[[tetraaqua(μ4-imidazole-4,5-dicarboxylato)(μ3-imidazole-4,5-dicarboxylato)-μ3-sulfato-μ2-sulfato-cobalt(II)digadolinium(III)] monohydrate]
The asymmetric unit of the title compound, {[CoGd(2)(C(5)H(2)N(2)O(4))(2)(SO(4))(2)(H(2)O)(4)]·H(2)O}(n), contains one Co(II) ion, two Gd(III) ions, two imidazole-4,5-dicarboxyl-ate ligands, two SO(4) (2-) anions, four coordinated water mol-ecules and one uncoordinated water mol-ecule. The Co(II) ion is six-coordinated by two O atoms from two coordinated water mol-ecules, as well as two O atoms...
متن کاملPoly[[tetraaqua(μ4-imidazole-4,5-dicarboxylato)(μ3-imidazole-4,5-dicarboxylato)-μ3-sulfato-μ2-sulfato-cobalt(II)dierbium(III)] monohydrate]
The asymmetric unit of the title compound, {[CoEr(2)(C(5)H(2)N(2)O(4))(2)(SO(4))(2)(H(2)O)(4)]·H(2)O}(n), contains a Co(II) ion, two Er(III) ions, two imidazole-4,5-dicarboxyl-ate (imdc) ligands, two SO(4) (2-) anions, four coordinated water mol-ecules and one uncoordinated water mol-ecule. The Co(II) ion is six-coordinated by two O atoms from two coordinated water mol-ecules and two O atoms an...
متن کاملPoly[[tetraaquabis(μ3-imidazole-4,5-dicarboxylato)tetrakis(μ2-imidazole-4,5-dicarboxylato)tricobalt(II)dilutetium(III)] dihydrate]
In the title compound, {[Co(3)Lu(2)(C(5)H(2)N(2)O(4))(6)(H(2)O)(4)]·2H(2)O}(n), the Lu(III) ions are seven-coordinated in a monocapped trigonal prismatic coordination geometry by six O atoms from three imidazole-4,5-dicarboxyl-ate ligands and one water O atom. The Co(II) ions are six-coordinated in a slightly distorted octa-hedral geometry and exhibit two types of coordination environments. One...
متن کاملPoly[diaqua(μ5-1H-imidazole-4,5-dicarboxylato)(μ4-1H-imidazole-4,5-dicarboxylato)trisilver(I)ytterbium(III)]
The asymmetric unit of the title compound, [Ag(3)Yb(C(5)HN(2)O(4))(2)(H(2)O)(2)](n), contains three Ag(I) ions, one Yb(III) ion, two imidazole-4,5-dicarboxyl-ate ligands and two coordinating water mol-ecules. The Yb(III) atom is eight-coordinated, in a bicapped trigonal prismatic coordination geometry, by six O atoms from three imidazole-4,5-dicarboxyl-ate ligands and two coordinating water mol...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010